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Tandem intermolecular [4 + 2] cycloadditions are catalysed by glycosylated enzymes for natural product biosynthesis

Jia-Wang Liu, Jiayan Lu, Chen Zhang, Qingyang Zhou, Cooper S. Jamieson, Changhui Shang, K. N. Houk, Jiahai Zhou, Youcai Hu

2023Nature Chemistry30 citationsDOI

Topics & Concepts

ChemistryCycloadditionGlycanEnzymeTandemBiosynthesisBiocatalysisCatalysisStereochemistryIntermolecular forceEnzyme catalysisCombinatorial chemistryBiochemistryGlycoproteinOrganic chemistryReaction mechanismMoleculeComposite materialMaterials sciencePlant biochemistry and biosynthesisMicrobial Natural Products and BiosynthesisGlycosylation and Glycoproteins Research
Tandem intermolecular [4 + 2] cycloadditions are catalysed by glycosylated enzymes for natural product biosynthesis | Litcius