Photocycloadditions in disparate chemical environments
David E. Marschner, Philipp W. Kamm, Hendrik Frisch, Andreas‐Neil Unterreiner, Christopher Barner‐Kowollik
Abstract
We elucidate the wavelength dependence of a photocycloaddition by (i) accessing action plots dependent on the reactivity relative to the number of absorbed photons, (ii) establishing the effect on substrate concentration on photochemical reactivity and (iii) determining wavelength-dependent reactivity as a function of the solvent environment, comparing acetonitrile with dimethyl sulfoxide.
Topics & Concepts
Reactivity (psychology)AcetonitrileDimethyl sulfoxideChemistryPhotochemistrySolventWavelengthSubstrate (aquarium)Organic chemistryMaterials scienceOptoelectronicsGeologyAlternative medicinePathologyMedicineOceanographyRadical Photochemical ReactionsPhotochromic and Fluorescence ChemistryPhotochemistry and Electron Transfer Studies