Discrimination of enantiomers for chiral molecules using analytically designed microwave pulses
Xun Gong, Yu Guo, Chengzhi Wang, Xiaobing Luo, Chuan‐Cun Shu
Abstract
ESST for chiral molecules can be achieved by controlling the delay time of the third optimized microwave pulse. We examine the robustness of such control schemes against the Rabi frequency and detuning errors and the environment effect through pure dephasing processes for practical applications. This work provides an alternative approach to analytically designing optimal control fields for quantum control of ESST by using complex pulse areas.
Topics & Concepts
EnantiomerMicrowaveMoleculeMaterials sciencePhysicsChemistryStereochemistryMolecular physicsComputational chemistryQuantum mechanicsSpectroscopy and Quantum Chemical StudiesLaser-Matter Interactions and ApplicationsQuantum Information and Cryptography