Fluorescence/Electrochemical Dual-Mode Sensor Based on a Nickel Metal-Organic Framework
Xue Wang, Huiying Sun, Xiao Li, Jing Sun, Zhong‐Min Su
Abstract
This study successfully developed a new dual-mode sensor material based on the nickel metal-organic framework (Ni-MOF) [Ni(tatrz) 1.5 (5-MIA)·H 2 O] (CUST-986) (tatrz = 1-(9-(1 H -1,2,4-triazol-1-yl)anthracen-10-yl)-1 H -1,2,4-triazole, 5-MIA = 5-methylisophthalic acid, CUST = Changchun University of Science and Technology) for a highly efficient detection of 2,4,6-trinitrophenol (TNP). In fluorescence sensing mode, CUST-986 demonstrates exceptional selective recognition capability for TNP, with a high quenching constant ( K sv ) of 1.676 × 10 5 M –1 and an ultralow detection limit (LOD) of 69.3 nM. In electrochemical detection mode, the modified electrode achieves a TNP detection limit of 0.48 μM. Real environmental sample tests show spike recovery rates of 80.3–93.6%, indicating good potential for practical applications with long-term stability. Through characterization techniques including powder X-ray diffraction, UV–vis, DFT calculations, and fluorescence lifetime measurements, the mechanism of electron transfer and the inner filter effect was elucidated. This bifunctional MOF sensor provides a new detection solution for environmental monitoring and public safety applications.