Twin-free, directly synthesized MFI nanosheets with improved thickness uniformity and their use in membrane fabrication
Donghun Kim, Supriya Ghosh, Nusnin Akter, Andrea Kraetz, Xuekui Duan, Gyeongseok Gwak, Neel Rangnekar, J.R. Johnson, Katabathini Narasimharao, Maqsood Ahmad Malik, Shaeel A. Al‐Thabaiti, Benjamin A. McCool, J. Anibal Boscoboinik, K. Andre Mkhoyan, Michael Tsapatsis
Abstract
Zeolite nanosheets can be used for the fabrication of low-defect-density, thin, and oriented zeolite separation membranes. However, methods for manipulating their morphology are limited, hindering progress toward improved performance. We report the direct synthesis (i.e., without using exfoliation, etching, or other top-down processing) of thin, flat MFI nanosheets and demonstrate their use as high-performance membranes for xylene isomer separations. Our MFI nanosheets were synthesized using nanosheet fragments as seeds instead of the previously used MFI nanoparticles. The obtained MFI nanosheets exhibit improved thickness uniformity and are free of rotational and MEL intergrowths as shown by transmission electron microscopy (TEM) imaging. The nanosheets can form well-packed nanosheet coatings. Upon gel-free secondary growth, the obtained zeolite MFI membranes show high separation performance for xylene isomers at elevated temperature (e.g., p -xylene flux up to 1.5 × 10 −3 mol m −2 s −1 and p -/ o -xylene separation factor of ~600 at 250°C).