Cellulose Nanocrystal Stabilized Liquid Metal Pickering Emulsion as Photothermal and Conductive Direct‐Writing Ink
Wang Sun, Zhen Zhang, Mengen Wang, Jiaqi Zeng, Liu Feng, Xiaojing Wang, Yali Hu, Chao Ma, Guofu Zhou
Abstract
Abstract Gallium‐based liquid metal (LM) has attracted great attention for constructing flexible electronic devices due to its excellent deformability and electrical conductivity. However, its large surface tension makes it difficult to be uniformly dispersed in polymers, which severely limits its wide applications. Hence, a surfactant‐free approach is proposed to prepare stable LM microspheres against precipitation and coalesce by facile ultrasonication via cellulose nanocrystal (CNC) stabilized LM‐in‐water Pickering emulsion (PE), where CNCs are employed as Pickering emulsifiers due their partial wettability with both LM and water phases, strong electrostatic adsorption and hydrogen bonding interactions with LM. So far, reports about LM PE and CNC‐stabilized inorganic material PE are still rare. CNC/LM PE is employed as direct‐writing inks on various substrates for delicate patterns. The pristine CNC/LM patterns show excellent photothermal conversion due to localized surface plasma resonance effect of CNC/LM microspheres. After activation by friction sintering, the LM patterns are highly electric conductive (1666.7 S m −1 ) due to the formation of LM connection. The activated LM patterns also displayed excellent Joule heating (83.2 °C at 0.9 V) and electromagnetic interference (EMI) shielding ability (585.7 dB mm −1 ) in X‐band range.