The Microstructure, Crystallization Behavior, and Mechanical Performance Evolutions of Li2O-Al2O3-SiO2 Glass and Glass–Ceramics with Different Alkaline Earth Oxide Modifications
Zheng Chi, Danni Li, Min Guo, Jihong Zhang, Jun Xie, Jianjun Han
Abstract
The introduction of alkaline earth oxides into Li2O-Al2O3-SiO2 glass components can improve the mechanical and optical performances of glass and glass–ceramics for various applications. In this research, microstructures, thermal properties, crystallization behavior, and mechanical performance changes in specific Li2O-Al2O3-SiO2 glass with the introduction of different alkali earth oxides, MgO, CaO, SrO, and BaO, were investigated. From Raman and NMR spectra microstructure analysis, it was confirmed that the addition of MgO could compete with Al as a network former and charge compensator, while increasing the bridging oxygen number with Si and affecting the chemical shift in 29Si. Meanwhile, the glass structures slightly changed due to the introduction of CaO, SrO, and BaO, with larger ionic radii. Meanwhile, the glass transition and first crystallization temperatures increased due to MgO introduction and then decreased with larger-radii alkali earth oxides’ addition, due to different glass network connectivity. After heat treatment, the crystal phases in the glass–ceramics changed with the introduction of alkaline earth oxides. The main crystal phases varied from Li2Si2O5, SiO2, and LiAlSi4O10 in glass without alkali earth oxide introduction; to SiO2, LixAlxSi3−xO6, and MgAl2Si4O12 in glass with MgO addition; to SiO2 and LixAlxSi3−xO6 with CaO addition; to SiO2, LiAlSi4O10, and Li2SiO3 for glass with SrO addition; and further to Li2SiO5, SiO2, and LiAlSi4O10 for glass with BaO addition. Moreover, in the mechanical performance of the glass–ceramics, the Vickers hardness and elastic modulus reached a maximum of 8.61 GPa for glass with MgO and 90.12 GPa for glass with BaO modification, respectively, probably due to different crystal phases. More importantly, the crack resistance values presented a large increase for MgO glass and MgO- or CaO-modified glass–ceramics.