Impact of sodium vanadium oxide (NaV<sub>3</sub>O<sub>8</sub>, NVO) material synthesis conditions on charge storage mechanism in Zn-ion aqueous batteries
Christopher R. Tang, Gurpreet Singh, Lisa M. Housel, Sung Joo Kim, Calvin D. Quilty, Yimei Zhu, Lei Wang, Kenneth J. Takeuchi, Esther S. Takeuchi, Amy C. Marschilok
Abstract
electrolyte using cyclic voltammetry, galvanostatic cycling, and rate capability testing. The thinner NVO(300) nanobelts (0.13 μm) demonstrate greater specific capacities and higher effective diffusion coefficients relative to the thicker NVO(500) nanorods. Notably however, while cells containing NVO(500) deliver lower specific capacity, they demonstrate enhanced capacity retention with cycling. The structural changes accompanying oxidation and reduction are elucidated via ex situ X-ray diffraction, transmission electron microscopy, and operando V K-edge X-ray absorption spectroscopy (XAS), where NVO material properties are shown to influence the ion insertion. Operando XAS verified that electron transfer corresponds directly to change in vanadium oxidation state, affirming vanadium redox as the governing electrochemical process.