Bis(pentafluorophenyl)-<i>o</i>-carborane and its arylthio derivatives: synthesis, electrochemistry and optical properties
Naoki Shida, Satoshi Owaki, Hiroshi Eguchi, Takanobu Nishikawa, Ikuyoshi Tomita, Shinsuke Inagi
Abstract
The synthesis of bis(pentafluorophenyl)-<italic>o</italic>-carborane is reported, which is further thiolated by nucleophilic aromatic substitution (S<sub>N</sub>Ar) reaction to give emissive materials in the solid state following aggregation-induced emission (AIE) fashion.
Topics & Concepts
CarboraneElectrochemistryChemistryCombinatorial chemistryOrganic chemistryComputational chemistryPhysical chemistryElectrodeBoron Compounds in ChemistryRadiopharmaceutical Chemistry and ApplicationsRadioactive element chemistry and processing