Presentation of gas-phase-reactant-accessible single-rhodium-atom catalysts for CO oxidation, <i>via</i> MOF confinement of an Anderson polyoxometalate
Qin Liu, Zhihengyu Chen, Hafeera Shabbir, Jiaxin Duan, Wentuan Bi, Zhiyong Lu, Neil M. Schweitzer, Selim Alayoǧlu, Subhadip Goswami, Karena W. Chapman, Rachel B. Getman, Qining Wang, Justin M. Notestein, Joseph T. Hupp
Abstract
Well-defined RhMo 6 O 24 n − clusters were encapsulated within a hierarchically porous MOF NU-1K and tested for an illustrative gas-phase CO oxidation reaction.
Topics & Concepts
PolyoxometalateRhodiumCatalysisGas phaseAtom (system on chip)PorosityPhase (matter)ChemistryChemical engineeringMaterials scienceInorganic chemistryCrystallographyNanotechnologyPhysical chemistryOrganic chemistryComputer scienceEmbedded systemEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCatalytic Processes in Materials Science