An unusual mechanism of building up of a high magnetization blocking barrier in an octahedral alkoxide Dy<sup>3+</sup>-based single-molecule magnet
Jérôme Long, Aleksei O. Tolpygin, Ekaterina Mamontova, Konstantin А. Lyssenko, Dan Liu, Munirah D. Albaqami, Liviu F. Chibotaru, Yannick Guari≠, Joulia Larionova≠, Alexander A. Trifonov
Abstract
We report a new octahedral luminescent SMM exhibiting massive crystal-field splitting and an anisotropic barrier of 1385 cm<sup>−1</sup>.
Topics & Concepts
OctahedronAlkoxideCrystallographyMaterials scienceMagnetizationAnisotropyCondensed matter physicsMagnetMoleculeMagnetic anisotropyCrystal structureChemistryMagnetic fieldPhysicsOpticsCatalysisQuantum mechanicsOrganic chemistryBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry