Switching from 2-pyridination to difluoromethylation: ligand-enabled nickel-catalyzed reductive difluoromethylation of aryl iodides with difluoromethyl 2-pyridyl sulfone
Wei Du, Qinyu Luo, Zhiqiang Wei, Xiu Wang, Chuanfa Ni, Jinbo Hu
Topics & Concepts
ReagentArylChemistrySulfoneCombinatorial chemistryReductive eliminationNickelCatalysisLigand (biochemistry)ElectrophilePhosphineBond cleavageMedicinal chemistryOrganic chemistryBiochemistryAlkylReceptorFluorine in Organic Chemistry