Exploring thiophene-2-acetate and thiophene-3-acetate binding modes towards the molecular and supramolecular structures and photoluminescence properties of Pb(<scp>ii</scp>) polymers
Mateusz Kowalik, Joanna Masternak, Katarzyna Kazimierczuk, Bogumiła Kupcewicz, Oleksiy V. Khavryuchenko, Barbara Barszcz
Abstract
The isomeric ligands thiophene-2(3)-acetate as linkers were used to construct Pb(<sc>ii</sc>) coordination polymers with an intriguing structure, noncovalent interactions, topology and interesting photoluminescence properties.
Topics & Concepts
ThiophenePhotoluminescenceSupramolecular chemistryPolymerMaterials sciencePolymer chemistryChemistryOrganic chemistryMoleculeOptoelectronicsMetal-Organic Frameworks: Synthesis and ApplicationsCrystal structures of chemical compoundsOrganometallic Compounds Synthesis and Characterization