A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2
Alexander Kroll, Henning Steinert, Lennart T. Scharf, Thorsten Scherpf, Bert Mallick, Viktoria H. Gessner
Abstract
Studies of the reactivity and coordination properties of the diamino-carbodiphosphorane <bold>1</bold> revealed that <bold>1</bold> is a weak N donor, but strongly coordinates <italic>via</italic> the carbon atom thus allowing the isolation of low-valent metal species.
Topics & Concepts
PlanarMonomerTrigonal crystal systemCrystallographyChemistryIsolation (microbiology)StereochemistryOrganic chemistryCrystal structureBioinformaticsPolymerBiologyComputer scienceComputer graphics (images)Synthesis and characterization of novel inorganic/organometallic compoundsN-Heterocyclic Carbenes in Organic and Inorganic ChemistryFerrocene Chemistry and Applications