Modeling and validation of hydrogen porosity formation in aluminum laser welding
Nicole Trometer, Buwei Chen, Michael P. Moodispaw, Wayne Cai, Teresa J. Rinker, Shardul Kamat, Zachary Velasco, Alan A. Luo
Abstract
Laser welding is used to weld aluminum alloy 1100 for battery cell manufacturing in the automotive industry. However, these welds can have porosity that can decrease their performance in the battery packs. One type of porosity is gas porosity, commonly understood to be due to hydrogen entrapment in the weld during solidification. Hydrogen is dissolved in the molten aluminum at elevated temperatures during laser heating and can be entrapped in the weld pool upon solidification. When welding anodized aluminum, the amount of hydrogen porosity is increased because the anodized oxide layer is broken up and the broken-up oxide can act as heterogeneous nucleation sites for hydrogen pores. A cellular automaton model has been developed to predict the nucleation and growth of hydrogen porosity during laser welding. This model has been validated with microstructure analysis, LECO® hydrogen analysis, and X-ray micro-computed tomography. This model can be used by welding engineers to reduce porosity and control weld quality during laser welding of aluminum alloys.