Thermodynamic and Molecular Analysis of Polar Adsorption Enthalpy: Modeling of Lewis Acid–Base Energetics at Solid Surfaces
Tayssir Hamieh
Abstract
) terms was found essential to reproduce experimental linearity and capture the physical duality of real surfaces. The new model thus transforms adsorption thermodynamics from an empirical linear model into a physically interpretable, statistically validated law. This formulation provides a unified energetic basis for describing the amphoteric and polarizable nature of oxides, polymers, and hybrid materials, and offers a predictive platform for future studies on temperature-dependent adsorption and electronic structure-surface energy correlations.
Topics & Concepts
AdsorptionChemistryCurvatureThermodynamicsInverse gas chromatographyEnthalpyPolarLewis acids and basesQuadratic equationEnergeticsChemical physicsPhysical chemistryPolarizabilityKinetic energySurface energyComputational chemistryCoupling (piping)InverseAcceptorRepresentation (politics)Statistical physicsIsing modelSurface (topology)Exothermic reactionImplicit solvationSurface chargeBinding energyAdsorption, diffusion, and thermodynamic properties of materialsChemical Thermodynamics and Molecular StructureAdsorption and biosorption for pollutant removal