Spectroelectrochemistry with Ultrathin Ion-Selective Membranes: Three Distinct Ranges for Analytical Sensing

Abstract

but also others) is initially accumulated into the membrane, we found three ranges of response for the absorbance: 10-950 nM for an accumulation-stripping protocol, 0.5-10 μM in diffusion-controlled cyclic voltammetry, and 0.5-32 mM with thin-layer cyclic voltammetry. This wide response range is a unique feature, one that is rare to find for a sensor and indeed for any analytical technique. Accordingly, the developed sensor is highly appealing for many analytical applications, especially considering the versatility of samples and ion analytes that may be spotted.

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