On‐Surface Synthesis of Organolanthanide Sandwich Complexes
Shanmugasibi K. Mathialagan, Sofía O. Parreiras, María Tenorio, Lenka Černá, Daniel Moreno, Beatriz Muñiz Cano, Cristina Navío, Manuel Valvidares, Miguel A. Valbuena, José I. Urgel, Pierluigi Gargiani, Rodolfo Miranda, Julio Camarero, José I. Martínez, José M. Gallego, David Écija
Abstract
The synthesis of lanthanide-based organometallic sandwich compounds is very appealing regarding their potential for single-molecule magnetism. Here, it is exploited by on-surface synthesis to design unprecedented lanthanide-directed organometallic sandwich complexes on Au(111). The reported compounds consist of Dy or Er atoms sandwiched between partially deprotonated hexahydroxybenzene molecules, thus introducing a distinct family of homoleptic organometallic sandwiches based on six-membered ring ligands. Their structural, electronic, and magnetic properties are investigated by scanning tunneling microscopy and spectroscopy, X-ray absorption spectroscopy, X-ray linear and circular magnetic dichroism, and X-ray photoelectron spectroscopy, complemented by density functional theory-based calculations. Both lanthanide complexes self-assemble in close-packed islands featuring a hexagonal lattice. It is unveiled that, despite exhibiting analogous self-assembly, the erbium-based species is magnetically isotropic, whereas the dysprosium-based compound features an in-plane magnetization.