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Interfacial Thermal Resistive Switching in (Pt,Cr)/SrTiO<sub>3</sub> Devices

Víctor Álvarez-Martínez, R. Ramos, Víctor Leborán, Alexandros Sarantopoulos, Regina Dittmann, F. Rivadulla

2024ACS Applied Materials & Interfaces13 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide The operation of oxide-based memristive devices relies on the fast accumulation and depletion of oxygen vacancies by an electric field close to the metal–oxide interface. Here, we show that the reversible change of the local concentration of oxygen vacancies at this interface also produces a change in the thermal boundary resistance (TBR), i.e., a thermal resistive switching effect. We used frequency domain thermoreflectance to monitor the interfacial metal–oxide TBR in (Pt,Cr)/SrTiO 3 devices, showing a change of ≈20% under usual SET/RESET operation voltages, depending on the structure of the device. Time-dependent thermal relaxation experiments suggest ionic rearrangement along the whole area of the metal/oxide interface, apart from the ionic filament responsible for the electrical conductivity switching. The experiments presented in this work provide valuable knowledge about oxide ion dynamics in redox-based memristive devices.

Topics & Concepts

Materials scienceThermalNanotechnologyOptoelectronicsEngineering physicsThermodynamicsPhysicsEngineeringAdvanced Memory and Neural ComputingFerroelectric and Piezoelectric MaterialsElectronic and Structural Properties of Oxides