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Coupling of amides with ketones <i>via</i> C–N/C–H bond cleavage: a mild synthesis of 1,3-diketones

Jiajia Chen, Yuanzhi Xia, Sunwoo Lee

2020Organic Chemistry Frontiers28 citationsDOI

Abstract

Amides react with enolizable ketones to give 1,3-diketones <italic>via</italic> C–N cleavage of amides and deprotonation of ketones.

Topics & Concepts

ChemistryDeprotonationCleavage (geology)Bond cleavageKetoneMedicinal chemistryStereochemistryCoupling (piping)Organic chemistryCatalysisIonMechanical engineeringEngineeringFracture (geology)Geotechnical engineeringAdvanced Synthetic Organic ChemistryCatalytic C–H Functionalization MethodsChemical Synthesis and Analysis
Coupling of amides with ketones <i>via</i> C–N/C–H bond cleavage: a mild synthesis of 1,3-diketones | Litcius