K<sub>2</sub>Cu<sub>3</sub>(Fe(CN)<sub>6</sub>)<sub>2</sub> In Situ-Modified MXene Nanosheets for Selective Enrichment of Cs<sup>+</sup> and the Mechanism
Jinchang Zhang, Xue‐Feng Cheng, Jicai Jiang, Apiladda Pattanateeradetch, Shuai Shi, Chanat Chokejaroenrat, Qingfeng Xu, Jianmei Lu
Abstract
Selective enrichment of cesium ions (Cs + ) at ultralow concentrations is essential for resource recovery and radioactive waste disposal, yet efficient adsorbents are lacking. Herein, we reported a Prussian blue analogue (K 2 Cu 3 (Fe(CN) 6 ) 2, Cu-PBA) decorated on MXene nanosheets by in situ fabrication, forming a composite material termed PMX, for enhanced adsorption of Cs + in acidic solutions and seawater. The stable, negatively charged MXene effectively anchors Cu 2+ precursors and promotes Cs + adsorption. The synergistic interaction between MXene and the in situ-synthesized Cu-PBA significantly enhances the adsorption performance and water stability of PMX in both acidic solutions and seawater. PMX achieves rapid adsorption equilibrium within 5 min, with a high adsorption capacity of 408.2 mg/g at pH 1, surpassing conventional adsorbents. Moreover, PMX shows excellent Cs + selectivity ( K d = 68,361.7 mL/g), cycle stability, and notable anti-irradiation ability, demonstrating superior efficiency in Cs + enrichment from complex matrices. The adsorption mechanism involves electrostatic attraction and K + /Cs + ion exchange, facilitated by MXene’s functional groups and the Cu-PBA structure. These findings underscore the excellent potential of PMX as an efficient adsorbent for resource enrichment and the removal of radioactive elements such as Cs + .