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Photo-catalyst-free photomediated pinacol coupling of ketones/aldehydes by formate at room temperature

Qing Shen, Kun Cao, Xueqin Chen, Xue Li, Naiyou Zhang, Yang‐Bao Miao, Jiahong Li

2023Green Chemistry25 citationsDOI

Abstract

In this work, a highly effective metal-free and photo-catalyst-free method for the reductive coupling of carbonyl compounds to produce pinacols using formate under photoirradiation has been reported.

Topics & Concepts

PinacolCatalysisFormateChemistryCoupling (piping)PhotochemistryMetalOrganic chemistryInorganic chemistryMaterials scienceMetallurgyRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques
Photo-catalyst-free photomediated pinacol coupling of ketones/aldehydes by formate at room temperature | Litcius