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Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction

А. А. Алексеенко, Angelina Pavlets, Elizaveta Moguchikh, M. I. Tolstunov, E. N. Gribov, С. В. Беленов, В. Е. Гутерман

2022Catalysts16 citationsDOIOpen Access PDF

Abstract

New highly active electrocatalysts were obtained by depositing bimetallic Pt-Cu nanoparticles on the surface of an N-doped carbon support. The structural–morphological characteristics and electrochemical behavior of the catalysts were studied. Using current stress testing protocols, their resistance to degradation was assessed in comparison with that of a commercial Pt/C material. A combined approach to catalyst synthesis that consists in alloying platinum with copper and doping the support makes it possible to obtain catalysts with a uniform distribution of bimetallic nanoparticles on the carbon surface. The obtained catalysts exhibit high activity and durability.

Topics & Concepts

Bimetallic stripElectrocatalystCatalysisMaterials sciencePlatinumNanoparticleChemical engineeringCarbon fibersElectrochemistryOxygen reductionDopingOxygen reduction reactionInorganic chemistryNanotechnologyElectrodeMetalMetallurgyChemistryComposite materialPhysical chemistryOrganic chemistryComposite numberEngineeringOptoelectronicsElectrocatalysts for Energy ConversionFuel Cells and Related MaterialsElectrochemical Analysis and Applications