Dielectric friction, violation of the Stokes-Einstein-Debye relation, and non-Gaussian transport dynamics of dipolar solutes in water
Tuhin Samanta, Dmitry V. Matyushov
Abstract
The authors explore the coupling between rotations and translations through electrostatic interactions with the medium and show that it leads to non-Gaussian translational dynamics and violation of Stokes-Einstein-Debye relation.
Topics & Concepts
DebyeDynamics (music)DipoleDielectricGaussianStatistical physicsRelation (database)Condensed matter physicsPhysicsMaterials scienceMechanicsChemical physicsQuantum mechanicsComputer scienceAcousticsDatabaseSpectroscopy and Quantum Chemical StudiesAdvanced Thermodynamics and Statistical MechanicsThermodynamic properties of mixtures