The missing MIL-101(Mn): geometrically guided synthesis and topologically correlated valence states
Yonghong Xiao, Mian Li, Jian-Rui Chen, Xin Lian, Yong‐Liang Huang, Xiao‐Chun Huang
Abstract
Through a geometrically guided approach, i.e. with the aid of pyridyl modulators, the long-sought MIL-101(Mn) structure is finally achieved, which features emergent topologically correlated mixed-valence states that are apt for enzymatic catalysis.
Topics & Concepts
Valence (chemistry)Valence bond theoryCrystallographyChemistryMaterials sciencePhysicsQuantum mechanicsMoleculeMolecular orbitalMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionSupramolecular Chemistry and Complexes