Towards clustered carbonyl cations [M<sub>3</sub>(CO)<sub>14</sub>]<sup>2+</sup> (M = Ru, Os): the need for innocent deelectronation
Malte Sellin, Christian Friedmann, Maximilian Mayländer, Sabine Richert, Ingo Krossing
Abstract
Trimeric M 3 (CO) 12 (M = Ru, Os) reacts with typical inorganic oxidants to unwanted side products. Yet, the 9,10-dichlorooctafluoroanthracene radical cation deelectronates these under CO pressure to give the first homotrimetallic [M 3 (CO) 14 ] 2+ salts.
Topics & Concepts
ChemistryRutheniumMedicinal chemistryCatalysisOrganic chemistryInorganic Fluorides and Related CompoundsAdvanced Chemical Physics StudiesAdvanced NMR Techniques and Applications