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Difluoroethylene Carbonate as an Electrolyte Additive for Engineering the Electrolyte–Electrode Interphase of Lithium Metal Batteries

Hanyu Tu, Shuo Li, Chang Liu, Zheng Luo, Lianshan Ni, Yinghao Zhang, Wentao Deng, Guoqiang Zou, Liangjun Zhou, Hongshuai Hou, Xiaobo Ji

2023ACS Applied Materials & Interfaces18 citationsDOI

Abstract

Difluoroethylene carbonate (DFEC) featuring abundant fluorine atoms has been proposed as a multifunctional electrolyte additive to boost the stability of the electrolyte-electrode interphase of lithium metal batteries. Thus, introducing the DFEC additive enables a high capacity retention rate of the Li||NCM811 full cell (up to 75% after 200 cycles) at 4.5 V high voltage.

Topics & Concepts

ElectrolyteMaterials scienceLithium metalInterphaseLithium (medication)ElectrodeInorganic chemistryCarbonateMetalChemical engineeringLithium carbonateIonMetallurgyOrganic chemistryIonic bondingChemistryPhysical chemistryBiologyMedicineGeneticsEndocrinologyEngineeringAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsAdvanced Battery Technologies Research
Difluoroethylene Carbonate as an Electrolyte Additive for Engineering the Electrolyte–Electrode Interphase of Lithium Metal Batteries | Litcius