Experimental Evidence of Chiral Symmetry Breaking in Kekulé-Ordered Graphene
Changhua Bao, Hong‐Yun Zhang, Teng Zhang, Xi Wu, Laipeng Luo, Shaohua Zhou, Qian Li, Yanhui Hou, Wei Yao, Liwei Liu, Pu Yu, Jia Li, Wenhui Duan, Hong Yao, Yeliang Wang, Shuyun Zhou
Abstract
The low-energy excitations of graphene are relativistic massless Dirac fermions with opposite chiralities at valleys K and K^{'}. Breaking the chiral symmetry could lead to gap opening in analogy to dynamical mass generation in particle physics. Here we report direct experimental evidences of chiral symmetry breaking (CSB) from both microscopic and spectroscopic measurements in a Li-intercalated graphene. The CSB is evidenced by gap opening at the Dirac point, Kekulé-O type modulation, and chirality mixing near the gap edge. Our work opens up opportunities for investigating CSB related physics in a Kekulé-ordered graphene.