The substituent effect on the spin-crossover behaviour in a series of mononuclear Fe(<scp>ii</scp>) complexes from thio-pybox ligands
Hai-Chao Liang, Yao Pan, Hai‐Lang Zhu, Yin‐Shan Meng, Chun‐Hua Liu, Tao Liu, Yuan‐Yuan Zhu
Abstract
The correlation of the SCO temperature and substituent electronegativity of ligands is observed and discussed for a family of [Fe(thio-pybox) 2 ] 2+ complexes.
Topics & Concepts
SubstituentThio-Series (stratigraphy)Spin crossoverChemistryStereochemistryMaterials scienceCrystallographyBiologyPaleontologyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies