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Improving Perovskite/CIGS Tandem Solar Cells for Higher Power Conversion Efficiency through Light Management and Bandgap Engineering

Guillermo A. Farias-Basulto, Thede Mehlhop, Nicolas Otto, Tobias Bertram, Klaus Jäger, Stefan Gall, Nikolaus Weinberger, Rutger Schlatmann, Iver Lauermann, R. Klenk, Emil List, Christian A. Kaufmann

2025ACS Applied Materials & Interfaces7 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide Perovskite and chalcopyrite materials are excellent absorbers for highly efficient, all-thin-film tandem solar cells. This work presents a certified world record for such a device, achieving a power conversion efficiency of 24.6 ± 1.1% under steady-state conditions. The best IV parameters extracted from certified current–voltage measurements presented a short-circuit current density of around 19.3 mA/cm 2, an open-circuit voltage of 1.765 V, and a fill factor of 71.8%. In comparison to our previous record, the current density improved considerably, mainly due to the lowering of the bandgap of the bottom subcell and the improved optics of the top perovskite cell.

Topics & Concepts

Materials scienceTandemOptoelectronicsEnergy conversion efficiencyPerovskite (structure)Band gapChalcopyriteVoltageCurrent densityEnergy transformationElectricity generationSolar energyPower (physics)Work (physics)Photovoltaic systemPower densityWide-bandgap semiconductorCurrent (fluid)Engineering physicsPower factorNanotechnologyPhotovoltaicsPerovskite solar cellSolar energy conversionCarbon nanotubePerovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And Properties