Formation of monomeric Sn(<scp>ii</scp>) and Sn(<scp>iv</scp>) perfluoropinacolate complexes and their characterization by <sup>119</sup>Sn Mössbauer and <sup>119</sup>Sn NMR spectroscopies
Jessica K. Elinburg, Ariel S. Hyre, James McNeely, Todd M. Alam, Steffen Klenner, Rainer Pöttgen, Arnold L. Rheingold, Linda H. Doerrer
Abstract
Sn(<sc>ii</sc>) and Sn(<sc>iv</sc>) perfluoropinacolate complexes were prepared and characterized with <sup>119</sup>Sn NMR,<sup>119</sup>Sn Mössbauer spectroscopy, and DFT calculations.
Topics & Concepts
Mössbauer spectroscopyTinMonomerCrystallographyNuclear magnetic resonance spectroscopyChemistrySpectroscopyCharacterization (materials science)Materials scienceStereochemistryNanotechnologyPhysicsPolymerOrganic chemistryQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganometallic Compounds Synthesis and Characterization