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Photoredox-catalyzed 2,2,2-trifluoroethylation and 2,2-difluoroethylation of alkenes with concomitant introduction of a quinoxalin-2(1<i>H</i>)-one moiety

Xiu Yang, Weidong Meng, Xiu‐Hua Xu, Yangen Huang

2021Organic Chemistry Frontiers35 citationsDOI

Abstract

A photoredox-catalyzed three-component radical cascade reaction of alkenes, quinoxalin-2(1 H )-ones, and ICH 2 CF 3 /ICH 2 CF 2 H is developed.

Topics & Concepts

ChemistryMoietyPhotoredox catalysisCatalysisCascadeMedicinal chemistryCombinatorial chemistryStereochemistryOrganic chemistryChromatographyPhotocatalysisFluorine in Organic Chemistry
Photoredox-catalyzed 2,2,2-trifluoroethylation and 2,2-difluoroethylation of alkenes with concomitant introduction of a quinoxalin-2(1<i>H</i>)-one moiety | Litcius