Photocatalytic CO<sub>2</sub>reduction sensitized by a special-pair mimic porphyrin connected with a rhenium(<scp>i</scp>) tricarbonyl complex
Yusuke Kuramochi, Ren Sato, Hiroki Sakuma, Akiharu Satake
Abstract
of ZnP-phen=Re was 170. The high activity in the system using the porphyrin dimer originates from no accumulation of the one-electron reduced species of the porphyrin that inhibit light absorption due to the inner-filter effect.
Topics & Concepts
RheniumPorphyrinPhotocatalysisReduction (mathematics)ChemistryPhotochemistryInorganic chemistryCatalysisOrganic chemistryMathematicsGeometryPorphyrin and Phthalocyanine ChemistryCO2 Reduction Techniques and CatalystsMetal-Catalyzed Oxygenation Mechanisms