Litcius/Paper detail

Metallic local-moment magnetocalorics as a route to cryogenic refrigeration

Thomas Gruner, Jiasheng Chen, Dong‐Jin Jang, Jacintha Banda, C. Geibel, M. Brando, F. M. Grosche

2024Communications Materials14 citationsDOIOpen Access PDF

Abstract

Abstract Commercial adiabatic demagnetisation refrigerators still employ the same hydrated salts that were first introduced over 85 years ago. The inherent limitations of these insulating magnetocalorics – poor thermal conductivity at sub-Kelvin temperatures, low entropy density, corrosiveness – can be overcome by a new generation of rare-earth based metallic magnetocalorics. Here, we present the metallic magnetocaloric YbNi 1.6 Sn as an attractive alternative to conventional refrigerants. YbNi 1.6 Sn retains high entropy into the 100 mK regime and avoids the noble metal constituents of alternative refrigerants. Demagnetisation tests demonstrate that YbNi 1.6 Sn enables economical and durable alternatives to traditional cooling devices for temperatures reaching below 120 mK. We find that the magnetocaloric properties of this material are facilitated by unusually small Kondo and RKKY interactions, which position YbNi 1.6 Sn in the extreme local moment limit on the generalised Kondo lattice phase diagram.

Topics & Concepts

RefrigerationMoment (physics)Materials scienceNuclear engineeringMechanical engineeringEngineeringPhysicsClassical mechanicsMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsOptical properties and cooling technologies in crystalline materials