Combining hydrogen bonding interactions with steric and electronic modifications for thermally robust α-diimine palladium catalysts toward ethylene (co)polymerization
Handou Zheng, Liu Zhong, Cheng Du, Wenbo Du, Chi Shing Cheung, Jingjing Ruan, Haiyang Gao
Abstract
Thermally robust α-diimine palladium catalysts are highly active for ethylene (co)polymerization at high temperatures by steric and electronic modifications in combination with hydrogen bonding interactions.
Topics & Concepts
Steric effectsDiiminePalladiumCatalysisEthylenePolymerizationHydrogen bondPhotochemistryPolymer chemistryChemistryElectronic effectHydrogenMaterials scienceOrganic chemistryPolymerMoleculeOrganometallic Complex Synthesis and CatalysisCatalytic Alkyne ReactionsCarbon dioxide utilization in catalysis