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The “<i>η</i>-sweet-spot” (<i>η</i><sub>max</sub>) in liquid-assisted mechanochemistry: polymorph control and the role of a liquid additive as either a catalyst or an inhibitor in resonant acoustic mixing (RAM)

Lori Gonnet, Tristan H. Borchers, Cameron B. Lennox, Jogirdas Vainauskas, Yong Teoh, Hatem M. Titi, Christopher J. Barrett, Stefan G. Koenig, Karthik Nagapudi, Tomislav Friščić

2022Faraday Discussions46 citationsDOI

Abstract

the reaction conversion drops off, demonstrating that the same liquid additive can act either as a catalyst or an inhibitor of a mechanochemical reaction, depending on the amount.

Topics & Concepts

MechanochemistryCatalysisBall millCarbodiimideChemistryBall (mathematics)Chemical engineeringCrystallographyAnalytical Chemistry (journal)Materials scienceOrganic chemistryComposite materialMathematicsMathematical analysisEngineeringYersinia bacterium, plague, ectoparasites researchPlant-based Medicinal ResearchAntimicrobial Resistance in Staphylococcus
The “<i>η</i>-sweet-spot” (<i>η</i><sub>max</sub>) in liquid-assisted mechanochemistry: polymorph control and the role of a liquid additive as either a catalyst or an inhibitor in resonant acoustic mixing (RAM) | Litcius