Transport and distribution of residual nitrogen in ion-adsorption rare earth tailings
Xiaolin Ou, Zhibiao Chen, Bengen Hong, Haiyan Wang, Liujun Feng, Youcun Liu, Mingyong Zhu, Zuliang Chen
Abstract
A large amount of nitrogen remains in ion-absorption rare earth tailings with in-situ leaching technology, and it continually ends up in groundwater sources. However, the distribution and transport of ammonium nitrogen (NH 4 + -N) and nitrate nitrogen (NO 3 − -N) across tailings with both depth and hill slopes is still unknown. In this study, the amount of NH 4 + -N and nitrate nitrogen (NO 3 − -N) was determined in tailings, and a soil column leaching experiment, served to assess the transport and distribution following mine closure. Firstly, a high concentration of NH 4 + -N in the leachate at the initial leaching stage was detected, up to 2000 mg L −1 , and the concentration of NH 4 + -N clearly diminished as time passed. Meanwhile, the NH 4 + -N contents remained relatively high in soil. Secondly, both the content of NH 4 + -N and NO 3 − -N varied greatly according to vertical distribution after leaching lasting several years. The amounts of NH 4 + -N and NO 3 − -N in surface soil were much smaller than those in deep soil, with 3–4 orders of magnitude variation with depth. Thirdly, when disturbed by NH 4 + -N, the pH not only diminished but also changed irregularly as depth increased. Fourthly, although the amount of NO 3 − -N was smaller than that of NH 4 + -N, both their distribution trend was similar with depth. In fact, NH 4 + -N and NO 3 − -N were significantly correlated but this declined from the knap to the piedmont. Based on these results, it is suggested that mining activity could cause nitrogen to be dominated by NH 4 + -N and acidification in a tailing even if leaching occurs over several years. NO 3 − -N derived from NH 4 + -N transports easily and it becomes the main nitrogen pollutant with the potential to be a long-lasting threat to the environment around a mine.