Deoxygenative C–S Bond Coupling with Sulfinates via Nickel/Photoredox Dual Catalysis
Shuai Zhong, Zhiwei Zhou, Feng Zhao, Guojiang Mao, Guo‐Jun Deng, Huawen Huang
Abstract
The C-S bond formation from aryl halides and thiols has been well established under various catalytic systems. In this work, user-friendly sulfinates have been exploited as an efficient sulfenylating reagent in the C-S couplings through visible-light-induced photo/nickel dual catalysis under base- and external reductant-free conditions. A large number of aryl sulfide products were accessed with high selectivity and high tolerance of various functionalities.
Topics & Concepts
ChemistryArylCatalysisNickelHalideReagentCombinatorial chemistrySulfideSelectivityCoupling (piping)PhotochemistryOrganic chemistryAlkylMechanical engineeringEngineeringSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsChemical Synthesis and Reactions