Efficient and Moisture Resistant Wide‐Bandgap Perovskite Solar Cells with Phosphinate‐Based Iodine Defect Passivation
Yuting Song, Ziyan Liu, Xinhang Cai, Haoyu Ge, Xuelian Liu, Xianzhao Wang, Xianzhao Wang, Aijun Li, Tsutomu Miyasaka, Naoyuki Shibayama, Xiaofeng Wang, Xiaofeng Wang
Abstract
Abstract Commercialization of perovskite‐based tandem solar cells requires preparing wide‐bandgap (WBG) perovskites in an ambient atmosphere environment. Here, producing high‐performance and stable WBG perovskite solar cells (PSCs) is demonstrated with blade coating in ambient air (≈60% relative humidity, RH) using sodium benzene phosphinate (SBP) as an additive modulator in the perovskite precursor. SBP can effectively suppress I − oxidation in high humidity ambient air, inhibit ion migration, and thus inhibit phase separation; it also modulates the crystallization of perovskite grains, passivates surface defects, and improves the hydrophobicity of perovskite film. The devices incorporating SBP achieved a power conversion efficiency (PCE) of up to 22.1%, which is the state‐of‐the‐art result for the WBG PSCs (≥1.68 eV) fabricated in ambient air with the blade coating method. In addition, the same protocol produces a PCE of 20.1% for a larger area cell (1.05 cm 2 ), and a PCE of over 19.5% for unit cells on a 100cm 2 substrate. The unencapsulated devices exhibit excellent stability, i.e., 90.3% efficiency retention after 2000 h with air exposure (≈60% RH) and 86.3% efficiency retention after 1000 h at 85 °C in an argon atmosphere. This SBP‐based material modulation for the preparation of WBG PSCs provides a new opportunity for manufacturing perovskite photovoltaics.