Enantiodivergent epoxidation of alkenes with a photoswitchable phosphate manganese-salen complex
Xiaofei Chen, Pieter J. Gilissen, Paul Tinnemans, Nicolas Vanthuyne, Floris P. J. T. Rutjes, Ben L. Feringa, Johannes A. A. W. Elemans, Roeland J. M. Nolte
Topics & Concepts
ChemistryCatalysisEnantiomerLigand (biochemistry)Chirality (physics)Supramolecular chemistryCombinatorial chemistryManganeseEpoxideEnantiomeric excessSubstrate (aquarium)Kinetic resolutionEnantioselective synthesisStereochemistryOrganic chemistryMoleculeReceptorQuarkPhysicsOceanographyBiochemistryChiral symmetry breakingGeologyQuantum mechanicsNambu–Jona-Lasinio modelPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryMolecular Sensors and Ion Detection