A Tetrahedral Bisacridine Donor Enables Fast Radiative Decay in Thermally Activated Delayed Fluorescence Emitter
Ranran Pei, Yulin Xu, Jingsheng Miao, Hao Peng, Zhanxiang Chen, Changjiang Zhou, He Liu, Chuluo Yang
Abstract
Abstract Achieving high efficiency and low efficiency roll‐off simultaneously is of great significance for further application of thermally activated delayed fluorescent (TADF) emitters. A balance between radiative decay and reversed intersystem crossing must be carefully established. Herein, we propose a qunolino‐acridine (QAc) donor composing two acridine with both planar (pAc) and bended (bAc) geometries. Combining with triazine, a TADF emitter QAc‐TRZ is assembled. The pAc provides a well interaction with triazine which ensures a decent TADF behavior, while the bAc offers a delocalization of highest occupied molecular orbital (HOMO) which guarantees an enhancement of radiative decay. Remarkably, QAc‐TRZ enables a highly efficient organic light emitting diode (OLED) with maximum external quantum efficiency (EQE) of 37.3 %. More importantly, the efficiencies under 100/1000 cd m −2 stay 36.3 % and 31.7 %, respectively, and remain 21.5 % even under 10 000 cd m −2 .