Spectroscopy, molecular structure, and electropolymerization of Ni(<scp>ii</scp>) and Cu(<scp>ii</scp>) complexes containing a thiophene-appending fluorinated Schiff base ligand
Guillermo Ahumada, Paul Hamon, Thierry Roisnel, Vincent Dorcet, Mauricio Fuentealba, Loreto A. Hernández, David Carrillo, Jean‐René Hamon, Carolina Manzur
Abstract
Electropolymerization of the title compounds yields golden-colored deposits, with the Cu( ii ) monomer enabling the formation of thicker coatings with increased conductivity in both CV and chronoamperometry voltammetric profiles.
Topics & Concepts
ThiopheneChemistrySchiff baseTrifluoromethylLigand (biochemistry)CrystallographyElectrochemistryStereochemistryPhysical chemistryOrganic chemistryElectrodeAlkylBiochemistryReceptorMetal complexes synthesis and propertiesMagnetism in coordination complexesOrganometallic Complex Synthesis and Catalysis