A carboxylate-assisted amination/unactivated C(sp<sup>2</sup>)–H arylation reaction <i>via</i> a palladium/norbornene cooperative catalysis
Yang An, Bo‐Sheng Zhang, Zhe Zhang, Ce Liu, Xue‐Ya Gou, Yanan Ding, Yong‐Min Liang
Abstract
A carboxylate-assisted palladium-catalysed Catellani reaction, which is compatible with <italic>ortho</italic>-amination and unactivated C(sp<sup>2</sup>)–H arylation, synthesized a series of 1-amino substituted dihydrophenanthridines, phenanthridines and 6<italic>H</italic>-benzo[<italic>c</italic>]chromenes.
Topics & Concepts
PalladiumAminationChemistryCarboxylateCatalysisNorborneneMedicinal chemistryStereochemistryOrganic chemistryPolymerizationPolymerCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsRadical Photochemical Reactions