Nanochannel-based {BaZn}–organic framework for catalytic activity on the cycloaddition reaction of epoxides with CO<sub>2</sub> and deacetalization-Knoevenagel condensation
Hongxiao Lv, Liming Fan, Hongtai Chen, Xiutang Zhang, Yan-Peng Gao
Abstract
at 55 °C, which can be ascribed to its structural advantages of nanoscale channels and rich bifunctional active sites. Moreover, NUC-51a could significantly accelerate the deacetalization-Knoevenagel condensation reaction in DMSO solvent at 70 °C.
Topics & Concepts
Knoevenagel condensationCatalysisCycloadditionBifunctionalChemistryPyridineLigand (biochemistry)Lewis acids and basesSolventNanoscopic scalePolymer chemistryMaterials scienceOrganic chemistryNanotechnologyBiochemistryReceptorMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications