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Novel 2-substituted-quinoxaline analogs with potential antiproliferative activity against breast cancer: insights into cell cycle arrest, topoisomerase II, and EGFR activity

Manar G. Salem, Sara A. Abu El-ata, Elsherbiny H. El‐Sayed, Suraj N. Mali, Hussah Abdullah Alshwyeh, Ghassan Almaimani, Riyad A. Almaimani, Hussain A. Almasmoum, Najla Altwaijry, Ebtesam Al‐Olayan, Essa M. Saied, Mohamed F. Youssef

2023RSC Advances25 citationsDOIOpen Access PDF

Abstract

= 33.7 ± 2.04 μM). Mechanistic studies revealed that compound 3b induced cell cycle arrest at the G1 transition and triggered apoptosis in MCF-7 cells, as evidenced by increasing the percentage of cells arrested in the G2/M and pre-G1 phases utilizing flow cytometric analysis and Annexin V-FITC/PI analysis. Moreover, compound 3b was found to substantially suppress topoisomerase enzyme activity in MCF-7 cells. Molecular modeling studies further supported the potential of compound 3b as a therapeutic candidate by demonstrating significant binding affinity to the active sites of both topoisomerase II and EGFR proteins. Taken together, the presented 2-substituted-quinoxaline analogues, especially compound 3b, show promise as potential candidates for the development of effective anti-breast cancer drugs.

Topics & Concepts

QuinoxalineCell cycle checkpointCoumarinTopoisomeraseChemistryCell cycleCancer researchMCF-7Breast cancerPharmacologyApoptosisCancerBiochemistryBiologyMedicineDNAHuman breastInternal medicineOrganic chemistrySynthesis and Biological EvaluationCancer therapeutics and mechanismsBioactive Compounds and Antitumor Agents