Thermal decomposition of mixed calcium oxalate hydrates – kinetic deconvolution of complex heterogeneous processes
Roman Svoboda, Zuzana Olmrová Zmrhalová, Dušan Galusek, D. Brandová, Jozef Chovanec
Abstract
. DSC on the other hand provided complex information on joint decomposition and carbon monoxide oxidation reactions - the proposed reaction mechanism includes completion of two reaction paths composed of consequent chemical reactions. A mechanistic view of the complex reaction path is discussed in terms of the diffusion barrier limiting the oxidation step.
Topics & Concepts
Calcium oxalateKinetic energyOxalateThermal decompositionDecompositionChemistryKineticsDeconvolutionHydrateCalciumChemical engineeringPyrolysisThermodynamicsMineralogyInorganic chemistryOrganic chemistryComputer sciencePhysicsAlgorithmEngineeringQuantum mechanicsThermal and Kinetic AnalysisEnergetic Materials and CombustionCrystallization and Solubility Studies