Heterogeneous Metallaphotocatalytic C(sp<sup>2</sup>)–C(sp<sup>3</sup>) Cross-Coupling Reactions with Integrated Bipyridyl-Ni(II)-Carbon Nitride
Xiao Dan, Qian Yang, Liuzhuang Xing, Yurong Tang, Wentao Wang, Yunfei Cai
Abstract
A fully heterogeneous metallaphotocatalytic C-C cross-coupling of aryl/vinyl halides with alkyl/allyltrifluoroborates has been developed by employing integrated bipyridyl-Ni(II)-carbon nitride as a stable and recyclable bifunctional catalyst. This visible-light-mediated heterogeneous protocol allows for the sustainable synthesis of diverse valuable diarylmethanes and allylarenes in high efficiency.
Topics & Concepts
BifunctionalChemistryHalideArylNitrideCarbon nitrideCoupling reactionCoupling (piping)Carbon fibersCatalysisAlkylInorganic chemistryOrganic chemistryMaterials scienceMetallurgyComposite numberLayer (electronics)PhotocatalysisComposite materialCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques