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Controlled assembly of cobalt embedded N-doped graphene nanosheets (Co@NGr) by pyrolysis of a mixed ligand Co(<scp>ii</scp>) MOF as a sacrificial template for high-performance electrocatalysts

Gopala Ram Bhadu, Bhavesh Parmar, Parth Patel, Jayesh C. Chaudhari, Eringathodi Suresh

2021RSC Advances16 citationsDOIOpen Access PDF

Abstract

current density was afforded at an overpotential of 390 mV for OER and 340 mV for HER respectively. This study provides insight for the development of cost-effective nonprecious element-based electrocatalysts for water splitting which has relevance in energy storage and conversion. Catalytic performance is governed by the synergistic compositional effect of metallic cobalt/nitrogen-doping in the graphitic carbon increasing the electrical conductivity/active sites of the composite material.

Topics & Concepts

CobaltPyrolysisGrapheneDopingMaterials scienceNanotechnologySupercapacitorLigand (biochemistry)Chemical engineeringChemistryInorganic chemistryElectrochemistryElectrodeReceptorOrganic chemistryOptoelectronicsPhysical chemistryBiochemistryEngineeringElectrocatalysts for Energy ConversionAdvanced battery technologies researchSupercapacitor Materials and Fabrication
Controlled assembly of cobalt embedded N-doped graphene nanosheets (Co@NGr) by pyrolysis of a mixed ligand Co(<scp>ii</scp>) MOF as a sacrificial template for high-performance electrocatalysts | Litcius