Coupling Ruthenium Bipyridyl and Cobalt Imidazolate Units in a Metal–Organic Framework for an Efficient Photosynthetic Overall Reaction in Diluted CO<sub>2</sub>
Ning‐Yu Huang, Jian‐Qiang Shen, Xuewen Zhang, Pei‐Qin Liao, Jie‐Peng Zhang, Xiao‐Ming Chen
Abstract
Artificial photocatalytic CO2 reduction, using water as the reductant, is challenging mainly because it is difficult for multiple functional units to cooperate efficiently. Here, we show that the classic photosensitive and H2O-oxidizing ruthenium bipyridyl units and CO2-reducing cobalt imidazolate units can be incorporated into a metal–organic framework using a classic organic ligand, imidazo[4,5-f][1,10]phenanthroline. Under visible light without additional sacrificial agents and photosensitizers, the overall conversion of CO2 and H2O to CO and O2 was achieved by the multifunctional photocatalyst in the CH3CN/H2O mixed solvent with a high CO production rate of 11.2 μmol g–1 h–1 and CO selectivity of ca. 100%. Thanks to its ultramicroporous structure with moderately strong CO2 adsorption ability, the photocatalyst also exhibited high performances with CO/CH4 production rates of 5.15/0.62 and 4.26/0.20 μmol g–1 h–1 in the gas phase with pure and even diluted CO2, respectively. Photoluminescence emission spectroscopy and photoelectrochemical tests confirmed that the photosensitive and catalytic units cooperated well to give suitable photocatalytic redox potentials and fast electron–hole separation.