Luminescent vapochromic single crystal to single crystal transition in one-dimensional coordination polymer featuring the first Cu(<scp>i</scp>) dimer bridged by an aqua ligand
Sloane Evariste, Ali Moustafa Khalil, Sébastien Kerneis, Chendong Xu, Guillaume Calvez, Karine Costuas, Christophe Lescop
Abstract
Vapochromic luminescence caused by included solvent mobility is observed in reversible single-crystal to single-crystal (SC–SC) transitions in a one-dimensional coordination polymer bearing the first reported water molecule bridging two Cu(<sc>i</sc>) ions.
Topics & Concepts
LuminescenceDimerCrystallographyCoordination polymerSingle crystalMoleculeLigand (biochemistry)IonBridging ligandSolventChemistryPolymerCrystal structureCrystal (programming language)Materials scienceStereochemistryReceptorOrganic chemistryOptoelectronicsProgramming languageBiochemistryComputer scienceMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes